Emi Yusa/Relationship, Hataraku Maou-sama! Wiki

Back in Ente Isla, they were mortal enemies. The Demon King's forces had destroyed Emilia's village, and her father was presumed killed. To take him down, she took up her duty as the Hero and trained harder than ever, rallying forces against the dark legions and leading them into battle. Maou remains more irritated by her presence than anything else, and despite her long hours of surveillance, she can find no trespass in his actions. Growing tired of watching him, she eventually questions whethe

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Emi Yusa/Synopsis, Hataraku Maou-sama! Wiki

Hataraku Maou-sama! Episode 2 — A wild tsundere appeared!