The Quintessential Quintuplets: 10 Reasons Why Nino Is The Best Quint

Nino is a classic tsundere in the anime/manga The Quintessential Quintuplets. She is mature, responsible, and initially expresses disdain for Futaro.

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List of The Quintessential Quintuplets characters - Wikipedia

The Quintessential Quintuplets, Vol. 8 by Negi Haruba